Concurrent Determination of U‐Pb Age and REE Mass Fractions of Zircon by High Mass Resolution SIMS

A combined geochronological and geochemical investigation for the same domain of zircon provides valuable information on timing and genesis, particularly in the case of multi‐growth metamorphic zircon. A high spatial resolution concurrent analytical method for zircon U‐Pb age and rare earth element content was successfully achieved in this study, using a multi‐collector secondary ion mass spectrometer (SIMS) at a ~ 8 μm diameter scale. Special instrument parameters were employed, including a high mass resolution of approximately 15000 applied to replace the previous energy filter method, and a dynamic multi‐collector mode used to reduce the measurement time to 18 min per analysis. Six zircon reference materials yielded precise and accurate ²⁰⁶Pb/²³⁸U ages, which are comparable to those obtained by the ordinary mono‐collector method, but with 2–3 times higher spatial resolution. All zircon grains measured in this study showed enriched heavy‐REE (HREE) contents consistent with previously reported values determined by LA and solution ICP‐MS methods. The light‐REE (LREE) mass fractions measured using both SIMS and LA‐ICP‐MS methods in this study, although with quite different volume, show consistent results within uncertainties.     

GNSS多天线基线网单历元模糊度同步解算法

提出多天线基线网单历元模糊度同步解算法，其具体实现步骤为：1）根据宽巷组合模糊度易于固定的优点，采用附加已知基线长度约束法同步解算各基线的宽巷模糊度，得到dm~cm级精度的近似基线分量；2）将解算得到的各近似基线分量作为约束，同步解算各基线的基频模糊度，以获取mm级精度的基线矢量。该方法的关键在于检验各历元宽巷模糊度解算的正确性，以获取可靠的近似基线分量，为解算各基线的基频模糊度提供准确的基线先验信息。由于动态情况下各历元观测信息比较少，单纯依赖ratio检验不可靠，提出结合基线误差、单位权中误差、基线网模糊度闭合环及ratio值等对多组宽巷模糊度进行检验，避免ratio值设置不当导致模糊度检验中发生纳伪和弃真问题。实测数据结果证明，该处理方法使得模糊度解算的成功率提高1%~2%，可以获取移动平台更丰富的导航信息，提高其服务能力。     

帕米尔高原Rushan-Pshart古特提斯洋或中特提斯洋争论的岩石地球化学证据

帕米尔高原上广泛分布的加里东期火山岩,印支期火山岩与燕山期火山岩被认为是块体依次向北俯冲拼贴到欧亚板块上的产物。特别是燕山期火山岩被认为是Rushan-Pshart中特提斯洋闭合的产物。但近年来地层古生物、火山岩证据不断表明Rushan-Pshart洋闭合时间在晚三叠一早侏罗世,由此限定Rushan-Pshart古特提斯洋性质,而帕米尔高原上广泛分布的燕山期火山岩是更南部的Shyok中特提斯洋闭合的产物。目前,中国境内Rushan-Pshart缝合带属性的研究工作展开较晚,研究程度较低。我们对塔什库尔干明铁盖沟一线燕山期火山岩带展开的工作发现零星分布的印支期花岗岩。印支期花岗岩错石U・Pb年龄显示岩体侵位时间在201 Ma左右。全岩主量元素特征表明岩石为I型高钾钙碱性闪长花岗岩;稀土元素在球粒陨石标准化图解中呈轻稀土元素相对富集,重稀土元素相对亏损的右倾海鸥型。明铁盖岩体的微量元素显示大离子亲石元素明显富集,而高场强元素明显亏损。稀土微量元素特征倾向花岗岩属性为岛弧型花岗岩,Sr-Nd-Hf同位素比值特征显示岩体形成于下地壳部分熔融环境。岩体的地化特征表明岩体形成的构造环境为板块汇聚的洋壳俯冲阶段,结合区域地质特征,我们将花岗岩体归为Rushan-Pshart古特提斯洋壳俯冲消减的产物。Rushan-Pshart缝合带传统上认为是中特提斯带,近年的研究进展认为其为古特提斯缝合带,本文的工作支持这种观点。Rushan-Pshart古特提斯缝合带的确立对帕米尔高原与青藏高原主体的块体对比提供了可信的对比方案,并对青藏高原新生代陆内变形方式的争论提供了可靠的证据。     

准噶尔盆地西北缘及玛湖凹陷沉积储集层研究进展*

准噶尔盆地西北缘玛湖凹陷中心区10×10⁸ t级砾岩大油区的发现,带动了该区沉积储集层研究的不断深入。作者梳理了准噶尔盆地西北缘及玛湖凹陷的沉积储集层研究现状和进展,认为准噶尔盆地西北缘及玛湖凹陷的沉积储集层研究的进展主要表现为: (1)提出了新的砂砾岩储集层岩石相和岩石学分析方法;(2)探索形成了新的沉积储集层地球物理测井和地震描述技术;(3)针对不同层系,在沉积物源、沉积相、沉积环境、沉积体系和沉积模式等方面取得大量新认识,建立了大型退覆式浅水缓坡扇三角洲沉积模式,指导油气勘探不断获得新突破;(4)在成岩作用理论指导下,所发现的储集层埋藏深度不断增加。研究表明,玛湖凹陷的沉积体系具有继承性: 从二叠纪到新近纪,发育了火山—碎屑岩沉积体系、细粒—蒸发盐沉积体系以及粗粒冲积扇、扇三角洲、辫状河三角洲等沉积体系,气候、构造和湖平面变化控制了沉积体系的形成和演化。沉积储集层研究为玛湖砾岩大油田的发现提供了有力的理论支持。未来应当加强针对古老层系和深部地层的沉积储集层研究工作,重视新理论新技术在西北缘和玛湖沉积储集层研究中的应用,已经形成的理论技术需要在勘探实践中接受进一步检验和完善。     

自然重砂成因矿物学特征及找矿指示作用

自然重砂是地质体经自然风化、剥蚀、搬运、沉积等地质作用而分离出的单矿物(或矿物组合)。自然重砂矿物晶体由于仍然保留有许多矿物成因信息,包括颜色、形态、化学成分、物理性质和矿物组合等特征,因此常用于追溯源区地质体或者找矿勘查。这种方法被认为是一种经济实用的找矿方法——自然重砂测量。本文基于全国自然重砂找矿的数据资料,系统梳理了自然重砂的矿物类型、出现频率及其分布等特点,分析了自然重砂的矿物组合和成因矿物学特征,研究了自然重砂矿物的源区烙印、搬运距离及标型指示矿物组合特征,探讨了自然重砂成因矿物学研究意义及其找矿应用前景。自然重砂矿物的颜色、形态及内部结构依然保留着明确的成因矿物学信息:其颜色和晶体形态具有继承性而与其源区母体联系起来,体现源区母体的特性;其矿物组成可分出残余原生重矿物(包括造岩矿物、副矿物、矿石矿物等)和新生重砂矿物两个部分,如赤铜矿、孔雀石等反映着源区岩性体的成分或者赋存状态特征,其矿物组合也在很大程度上继承原生共生矿物而体现诸如有无矿化等意义;重砂颗粒的磨圆度、边界光滑性等表面特征反映搬运距离,有利于明确响应源区母体或者物源,而具有良好的找矿指示意义。     

紫外-可见分光光度法测定多花黄精多糖含量

目的：测定湖南洪江国家黄精标准化基地多花黄精中的多糖含量，为多花黄精的进一步开发利用及药材质量标准研究奠定基础。方法：以葡萄糖为标准品，采用硫酸-蒽酮试剂显色，应用紫外-可见分光光度法测定多花黄精多糖含量。结果：葡萄糖在3.28～19.68μg/mL范围内线性良好（r=0.9992），多花黄精多糖平均含量为8.05%。结论：洪江种植基地的多花黄精品质优良，洪江是道地黄精药材种植理想基地。     

Relationship Between Electrical Properties and Sedimentary Environment of the Longmaxi Formation Shale, Southern Sichuan

The Lower Silurian Longmaxi Formation in the south of Sichuan is a key player in the exploration and development of shale gas in China. Due to a highly complex topographic area, electromagnetic methods (EM) become important exploration means in this area. Many studies have been conducted on the shale mineral composition and electrical properties of shale, however, the correlation between sedimentary environments and the electrical properties of shale remain poorly understood. The electrical properties and sedimentary environment of the organic-rich shale of the Longmaxi Formation have been studied by means of X-ray diffraction, organic geochemistry, scanning electron microscopy and complex resistivity measurements. The discovered high quartz content of the Longmaxi Formation shale results in low resistivity. Deep-water shelf biogenic quartz contributes lower resistivity more than that of shallow-water terrigenous quartz. The deep-water anoxic and organic sedimentary environment led to major enrichment of pyrite, leading to a high polarization effect in shale. We present the correlation between the lithofacies types and electrical properties of Longmaxi Formation. The mixed siliceous shale lithofacies is the most favorable among the three lithofacies, which is characterized by high total organic carbon (TOC) content, high brittleness mineral content, high polarization and low resistivity (“three high and one low”). This feature is an effective identification of shale gas reservoirs by electromagnetic prospecting. Our study can provide constraints on electrical parameters of rocks for electromagnetic “sweet spot” exploration of shale gas, and so this has important geological significance to shale gas exploration and development.     

基于分布式控制力矩陀螺的水下航行器轨迹跟踪控制

基于控制力矩陀螺群(CMGs)的水下航行器具有低速或零速机动的能力。采用基于分布式CMGs的水下航行器方案,并研究其水平面的轨迹跟踪控制问题。通过全局微分同胚变换将非完全对称的动力学模型解耦成标准欠驱动控制模型,并根据简化的模型构建其轨迹跟踪的误差动力学模型,将轨迹跟踪控制问题转化为误差模型镇定问题。基于一种分流神经元模型和反步法设计了系统的轨迹跟踪控制律,该控制器不需要对任何虚拟控制输入进行求导计算,且能确保跟踪误差的最终一致有界性。仿真结果表明该控制器能够实现在不依赖动力学参数先验知识的情况下对光滑轨迹的有效跟踪。     

不同类型的高位虾池排污对秋茄幼苗生长的影响

中国多数红树林陆地边缘存在着大量的养虾池塘。这些养虾池塘可通过：（1）换塘外排废水，（2）清塘直排污泥影响周围的红树林。本研究共包含两个实验，来探讨这两种类型的排污对秋茄幼苗生长的影响。实验一模拟虾池常规换塘情况，研究换塘废水对秋茄幼苗生长的影响。实验二设置四种虾池清塘污泥沉积厚度（0 cm，2 cm，4 cm，8 cm），研究虾池清塘污泥的累积效应对秋茄幼苗生长的影响。结果如下：在5，15和25三种盐度下，虾池换塘废水未对秋茄生长指标造成显著影响；而清塘污泥对秋茄生长的影响与其沉积厚度有关，大多数生长参数在污泥沉积厚度为4 cm时呈现最大值。秋茄幼苗在适量的沉积厚度下加速了生长，且本实验秋茄幼苗对虾池清塘污泥的耐受性为沉积厚度8 cm。     

Consolidation of double‐layered ground with vertical drains

Vertical drains are usually installed in subsoil consisting of several layers. Due to the complex nature of the problem, over the past decades, the consolidation properties of multi‐layered ground with vertical drains have been analysed mainly by numerical methods. An analytical solution for consolidation of double‐layered ground with vertical drains under quasi‐equal strain condition is presented in this paper. The main steps for the computation procedure are listed. The convergence of the series solution is discussed. The comparisons between the results obtained by the present analytical method and the existing numerical solutions are described by figures. The orthogonal relation for the system of double‐layered ground with vertical drains is proven. Finally, some consolidation properties of double‐layered ground with vertical drains are analysed. Copyright © 2001 John Wiley & Sons, Ltd.